| 1st Qualifying Round | 2nd Qualifying Round | 3rd Qualifying Round | Playoffs | League Phase | Knockout |
| Round of 16 | Quarterfinals | Semifinals |
Round:
Played
1st Round
03/04/2025 - Tuesday
12:45
Club Brugge
1
x
3
Aston Villa
15:00
Borussia Dortmund
1
x
1
Lille
15:00
PSV Eindhoven
1
x
7
Arsenal
15:00
Real Madrid
2
x
1
Atlético de Madrid
03/05/2025 - Wednesday
12:45
Feyenoord
0
x
2
Internazionale
15:00
Bayern Munich
3
x
0
Bayer Leverkusen
15:00
Benfica
0
x
1
Barcelona
15:00
Paris Saint-Germain
0
x
1
Liverpool
2nd Round
03/11/2025 - Tuesday
13:45
Barcelona
3
x
1
Benfica
16:00
Bayer Leverkusen
0
x
2
Bayern Munich
16:00
Internazionale
2
x
1
Feyenoord
16:00
Liverpool
0
Pen
1*
Paris Saint-Germain
03/12/2025 - Wednesday
13:45
Lille
1
x
2
Borussia Dortmund
16:00
Arsenal
2
x
2
PSV Eindhoven
16:00
Aston Villa
3
x
0
Club Brugge
16:00
Atlético de Madrid
1
Pen
0*
Real Madrid